Abstract
1. The acylation of 1,3,3-trisubstituted diaziridines with acyl chlorides is realized primarily at the substituted N1 atom and is accompanied by diaziridine-hydrazone rearrangement. 2. Acylation with a 0.5-mole amount of (S)-N-tosylproline chloride is an effective method for the optical activation of 1,3,3-trialkyldiaziridines and can be used to determine the absolute configurations of these compounds.
Original language | English |
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Pages (from-to) | 1665-1671 |
Number of pages | 7 |
Journal | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
Volume | 37 |
Issue number | 8 |
DOIs | |
State | Published - Aug 1988 |
Externally published | Yes |