TY - JOUR
T1 - An extension of the quadrant rule in oxiranes to non-alkyl substituents
T2 - the CD of R (-)- and S (+)-epichlorohydrin
AU - Basil, Anat
AU - Ben-Tzur, Sara
AU - Gedanken, Aharon
AU - Rodger, Alison
PY - 1991/5/31
Y1 - 1991/5/31
N2 - The circular dichroism (CD) of epichlorohydrin (1-chloro-2,3-epoxypropane) in the gas phase reveals one structureless broad band peaked at 1710 Å. The CD sign of this band is according to the prediction made by the quadrant rule previously established for the oxirane chromophore. It seems that the quadrant rule can be applied to substituents other than alkyl groups.
AB - The circular dichroism (CD) of epichlorohydrin (1-chloro-2,3-epoxypropane) in the gas phase reveals one structureless broad band peaked at 1710 Å. The CD sign of this band is according to the prediction made by the quadrant rule previously established for the oxirane chromophore. It seems that the quadrant rule can be applied to substituents other than alkyl groups.
UR - http://www.scopus.com/inward/record.url?scp=0042616644&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(91)85154-o
DO - 10.1016/0009-2614(91)85154-o
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AN - SCOPUS:0042616644
SN - 0009-2614
VL - 180
SP - 482
EP - 484
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 5
ER -