An easy method for the production of functional polypyrrole/MWCNT and polycarbazole/MWCNT composites using nucleophilic multi-walled carbon nanotubes

Diana Goldman; Jean Paul Lellouche

doi:10.1016/j.carbon.2010.07.032

An easy method for the production of functional polypyrrole/MWCNT and polycarbazole/MWCNT composites using nucleophilic multi-walled carbon nanotubes

Diana Goldman, Jean Paul Lellouche

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Oxidized polycarboxylated multi-walled carbon nanotubes (COOH-MWCNTs) may be readily decorated by covalently attached pyrrolyl (Pyr) and carbazolyl (Cbz)-containing ligands. Resulting chemically modified MWCNTs behave as a novel nucleophilic nanosized phase. It covalently trapped positively charged polyPyr- and polyCbz-chains grown oxidatively in bulk media of liquid phase polymerizations (LPPs). This two-step sequence for the controlled fabrication of functional (polyCOOH) dual phase polyPyr/MWCNT and polyCbz/MWCNT composites provided a general solution to the observed detrimental issues of phase compatibility during component assembly. In one specific case, this multi-parameter oxidative liquid phase polymerization process has been also investigated using a statistically relevant design of experiments in order to evaluate influential LPP parameters for process optimization.

Original language	English
Pages (from-to)	4170-4177
Number of pages	8
Journal	Carbon
Volume	48
Issue number	14
DOIs	https://doi.org/10.1016/j.carbon.2010.07.032
State	Published - Nov 2010

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10.1016/j.carbon.2010.07.032

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title = "An easy method for the production of functional polypyrrole/MWCNT and polycarbazole/MWCNT composites using nucleophilic multi-walled carbon nanotubes",

abstract = "Oxidized polycarboxylated multi-walled carbon nanotubes (COOH-MWCNTs) may be readily decorated by covalently attached pyrrolyl (Pyr) and carbazolyl (Cbz)-containing ligands. Resulting chemically modified MWCNTs behave as a novel nucleophilic nanosized phase. It covalently trapped positively charged polyPyr- and polyCbz-chains grown oxidatively in bulk media of liquid phase polymerizations (LPPs). This two-step sequence for the controlled fabrication of functional (polyCOOH) dual phase polyPyr/MWCNT and polyCbz/MWCNT composites provided a general solution to the observed detrimental issues of phase compatibility during component assembly. In one specific case, this multi-parameter oxidative liquid phase polymerization process has been also investigated using a statistically relevant design of experiments in order to evaluate influential LPP parameters for process optimization.",

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N2 - Oxidized polycarboxylated multi-walled carbon nanotubes (COOH-MWCNTs) may be readily decorated by covalently attached pyrrolyl (Pyr) and carbazolyl (Cbz)-containing ligands. Resulting chemically modified MWCNTs behave as a novel nucleophilic nanosized phase. It covalently trapped positively charged polyPyr- and polyCbz-chains grown oxidatively in bulk media of liquid phase polymerizations (LPPs). This two-step sequence for the controlled fabrication of functional (polyCOOH) dual phase polyPyr/MWCNT and polyCbz/MWCNT composites provided a general solution to the observed detrimental issues of phase compatibility during component assembly. In one specific case, this multi-parameter oxidative liquid phase polymerization process has been also investigated using a statistically relevant design of experiments in order to evaluate influential LPP parameters for process optimization.

AB - Oxidized polycarboxylated multi-walled carbon nanotubes (COOH-MWCNTs) may be readily decorated by covalently attached pyrrolyl (Pyr) and carbazolyl (Cbz)-containing ligands. Resulting chemically modified MWCNTs behave as a novel nucleophilic nanosized phase. It covalently trapped positively charged polyPyr- and polyCbz-chains grown oxidatively in bulk media of liquid phase polymerizations (LPPs). This two-step sequence for the controlled fabrication of functional (polyCOOH) dual phase polyPyr/MWCNT and polyCbz/MWCNT composites provided a general solution to the observed detrimental issues of phase compatibility during component assembly. In one specific case, this multi-parameter oxidative liquid phase polymerization process has been also investigated using a statistically relevant design of experiments in order to evaluate influential LPP parameters for process optimization.

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An easy method for the production of functional polypyrrole/MWCNT and polycarbazole/MWCNT composites using nucleophilic multi-walled carbon nanotubes

Abstract

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