Aminoamidines. 5. Synthesis and acetylation of N,N1,N2-triaryl-substituted β-aminoamidines

E. E. Korshin; L. G. Zakharova; Ya A. Levin; L. Kh Ashrafullina; E. A. Podval'nyi; Yu Ya Efremov

doi:10.1007/bf00863377

Aminoamidines. 5. Synthesis and acetylation of N,N¹,N²-triaryl-substituted β-aminoamidines

E. E. Korshin
, L. G. Zakharova
, Ya A. Levin
, L. Kh Ashrafullina
, E. A. Podval'nyi
, Yu Ya Efremov

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Triaryl-substituted β-aminoamidines were obtained by the reaction of α,β-unsaturated N-arylimidoyl chlorides with arylamines. Acylation of the products gave the products from monosubstitution at the β-amino group. Triaryl-substituted β-aminoamidines react with phosgene and with oxalyl chloride to form 4-aryliminoperhydropyrimidin-2-ones and 5-aryliminoperhydro-1,4-diazepine-2,3-diones, respectively.

Original language	English
Pages (from-to)	2082-2090
Number of pages	9
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	41
Issue number	11
DOIs	https://doi.org/10.1007/bf00863377
State	Published - Nov 1992

Keywords

acylation
binucleophile
heterocycle
oxalyl chloride
phosgene
synthesis
β-aminoamidine

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10.1007/bf00863377

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title = "Aminoamidines. 5. Synthesis and acetylation of N,N1,N2-triaryl-substituted β-aminoamidines",

abstract = "Triaryl-substituted β-aminoamidines were obtained by the reaction of α,β-unsaturated N-arylimidoyl chlorides with arylamines. Acylation of the products gave the products from monosubstitution at the β-amino group. Triaryl-substituted β-aminoamidines react with phosgene and with oxalyl chloride to form 4-aryliminoperhydropyrimidin-2-ones and 5-aryliminoperhydro-1,4-diazepine-2,3-diones, respectively.",

keywords = "acylation, binucleophile, heterocycle, oxalyl chloride, phosgene, synthesis, β-aminoamidine",

author = "Korshin, \{E. E.\} and Zakharova, \{L. G.\} and Levin, \{Ya A.\} and Ashrafullina, \{L. Kh\} and Podval'nyi, \{E. A.\} and Efremov, \{Yu Ya\}",

year = "1992",

month = nov,

doi = "10.1007/bf00863377",

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T1 - Aminoamidines. 5. Synthesis and acetylation of N,N1,N2-triaryl-substituted β-aminoamidines

AU - Korshin, E. E.

AU - Zakharova, L. G.

AU - Levin, Ya A.

AU - Ashrafullina, L. Kh

AU - Podval'nyi, E. A.

AU - Efremov, Yu Ya

PY - 1992/11

Y1 - 1992/11

N2 - Triaryl-substituted β-aminoamidines were obtained by the reaction of α,β-unsaturated N-arylimidoyl chlorides with arylamines. Acylation of the products gave the products from monosubstitution at the β-amino group. Triaryl-substituted β-aminoamidines react with phosgene and with oxalyl chloride to form 4-aryliminoperhydropyrimidin-2-ones and 5-aryliminoperhydro-1,4-diazepine-2,3-diones, respectively.

AB - Triaryl-substituted β-aminoamidines were obtained by the reaction of α,β-unsaturated N-arylimidoyl chlorides with arylamines. Acylation of the products gave the products from monosubstitution at the β-amino group. Triaryl-substituted β-aminoamidines react with phosgene and with oxalyl chloride to form 4-aryliminoperhydropyrimidin-2-ones and 5-aryliminoperhydro-1,4-diazepine-2,3-diones, respectively.

KW - acylation

KW - binucleophile

KW - heterocycle

KW - oxalyl chloride

KW - phosgene

KW - synthesis

KW - β-aminoamidine

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SN - 0568-5230

VL - 41

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EP - 2090

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 11

ER -

Aminoamidines. 5. Synthesis and acetylation of N,N¹,N²-triaryl-substituted β-aminoamidines

Abstract

Keywords

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