A synthesis of (-) supinidine and its regioisomer by intramolecular oxime olefin cycloaddition.

Alfred Hassner; Suddham Singh; Raman Sharma; Rakesh Maurya

doi:10.1016/S0040-4020(01)80375-6

A synthesis of (-) supinidine and its regioisomer by intramolecular oxime olefin cycloaddition.

Alfred Hassner, Suddham Singh, Raman Sharma, Rakesh Maurya

Department of Chemistry

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Abstract

A synthesis of (-) supinidine 1 and its regioisomer 2 from L-proline is described. The key step is a thermal intramolecular oxime-olefin cycloaddition; dimerization products resulting from intramolecular nitrone formation were also isolated.

Original language	English
Pages (from-to)	2317-2324
Number of pages	8
Journal	Tetrahedron
Volume	49
Issue number	11
DOIs	https://doi.org/10.1016/S0040-4020(01)80375-6
State	Published - 12 Mar 1993

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title = "A synthesis of (-) supinidine and its regioisomer by intramolecular oxime olefin cycloaddition.",

abstract = "A synthesis of (-) supinidine 1 and its regioisomer 2 from L-proline is described. The key step is a thermal intramolecular oxime-olefin cycloaddition; dimerization products resulting from intramolecular nitrone formation were also isolated.",

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AU - Singh, Suddham

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AU - Maurya, Rakesh

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AB - A synthesis of (-) supinidine 1 and its regioisomer 2 from L-proline is described. The key step is a thermal intramolecular oxime-olefin cycloaddition; dimerization products resulting from intramolecular nitrone formation were also isolated.

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A synthesis of (-) supinidine and its regioisomer by intramolecular oxime olefin cycloaddition.

Abstract

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