A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine

Juan José Cid; John Mohanraj; Meera Mohankumar; Michel Holler; Gianluca Accorsi; Lydia Brelot; Iwona Nierengarten; Omar Moudam; Adrien Kaeser; Béatrice Delavaux-Nicot; Nicola Armaroli; Jean François Nierengarten

doi:10.1039/c2cc37873f

A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine

Juan José Cid, John Mohanraj, Meera Mohankumar, Michel Holler, Gianluca Accorsi, Lydia Brelot, Iwona Nierengarten, Omar Moudam, Adrien Kaeser, Béatrice Delavaux-Nicot, Nicola Armaroli, Jean François Nierengarten

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31 Scopus citations

Abstract

Treatment of 2-diphenylphosphino-6-methylpyridine (dpPyMe) with Cu(CH₃CN)₄BF₄ afforded the stable dinuclear Cu(I) complex [Cu₂(μ-dpPyMe)₃(CH₃CN)](BF₄)₂. This compound is a weak emitter in solution, however a remarkably high emission quantum yield (46%) has been found in a rigid matrix at room temperature.

Original language	English
Pages (from-to)	859-861
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	9
DOIs	https://doi.org/10.1039/c2cc37873f
State	Published - 2 Jan 2013
Externally published	Yes

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Cid, J. J., Mohanraj, J., Mohankumar, M., Holler, M., Accorsi, G., Brelot, L., Nierengarten, I., Moudam, O., Kaeser, A., Delavaux-Nicot, B., Armaroli, N., & Nierengarten, J. F. (2013). A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine. Chemical Communications, 49(9), 859-861. https://doi.org/10.1039/c2cc37873f

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title = "A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine",

abstract = "Treatment of 2-diphenylphosphino-6-methylpyridine (dpPyMe) with Cu(CH3CN)4BF4 afforded the stable dinuclear Cu(I) complex [Cu2(μ-dpPyMe)3(CH3CN)](BF4)2. This compound is a weak emitter in solution, however a remarkably high emission quantum yield (46%) has been found in a rigid matrix at room temperature.",

author = "Cid, {Juan Jos{\'e}} and John Mohanraj and Meera Mohankumar and Michel Holler and Gianluca Accorsi and Lydia Brelot and Iwona Nierengarten and Omar Moudam and Adrien Kaeser and B{\'e}atrice Delavaux-Nicot and Nicola Armaroli and Nierengarten, {Jean Fran{\c c}ois}",

year = "2013",

month = jan,

day = "2",

doi = "10.1039/c2cc37873f",

language = "אנגלית",

volume = "49",

pages = "859--861",

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publisher = "Royal Society of Chemistry",

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Cid, JJ, Mohanraj, J, Mohankumar, M, Holler, M, Accorsi, G, Brelot, L, Nierengarten, I, Moudam, O, Kaeser, A, Delavaux-Nicot, B, Armaroli, N & Nierengarten, JF 2013, 'A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine', Chemical Communications, vol. 49, no. 9, pp. 859-861. https://doi.org/10.1039/c2cc37873f

TY - JOUR

T1 - A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine

AU - Cid, Juan José

AU - Mohanraj, John

AU - Mohankumar, Meera

AU - Holler, Michel

AU - Accorsi, Gianluca

AU - Brelot, Lydia

AU - Nierengarten, Iwona

AU - Moudam, Omar

AU - Kaeser, Adrien

AU - Delavaux-Nicot, Béatrice

AU - Armaroli, Nicola

AU - Nierengarten, Jean François

PY - 2013/1/2

Y1 - 2013/1/2

N2 - Treatment of 2-diphenylphosphino-6-methylpyridine (dpPyMe) with Cu(CH3CN)4BF4 afforded the stable dinuclear Cu(I) complex [Cu2(μ-dpPyMe)3(CH3CN)](BF4)2. This compound is a weak emitter in solution, however a remarkably high emission quantum yield (46%) has been found in a rigid matrix at room temperature.

AB - Treatment of 2-diphenylphosphino-6-methylpyridine (dpPyMe) with Cu(CH3CN)4BF4 afforded the stable dinuclear Cu(I) complex [Cu2(μ-dpPyMe)3(CH3CN)](BF4)2. This compound is a weak emitter in solution, however a remarkably high emission quantum yield (46%) has been found in a rigid matrix at room temperature.

UR - http://www.scopus.com/inward/record.url?scp=84872077945&partnerID=8YFLogxK

U2 - 10.1039/c2cc37873f

DO - 10.1039/c2cc37873f

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SN - 1359-7345

VL - 49

SP - 859

EP - 861

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine

Abstract

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