A ruthenium-carbamato-complex derived from a siloxylated amine and carbon dioxide for the oxidative α-cyanation of aromatic and cyclic tertiary amines

Subodh Kumar; Pawan Kumar; Suman L. Jain

doi:10.1039/c3ra44051f

A ruthenium-carbamato-complex derived from a siloxylated amine and carbon dioxide for the oxidative α-cyanation of aromatic and cyclic tertiary amines

Subodh Kumar, Pawan Kumar, Suman L. Jain

CSIR - Indian Institute of Petroleum

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The ruthenium carbamate complex derived from 3-trimethoxysilyl-1-propyl amine and carbon dioxide was found to be a novel catalyst for the oxidative cyanation of aromatic and cyclic tertiary amines to corresponding α-amino nitriles in high to excellent yields by using hydrogen peroxide and molecular oxygen as enviro-economic oxidants. The developed protocol suggested an efficient alternative for recycling carbon dioxide.

Original language	English
Pages (from-to)	24013-24016
Number of pages	4
Journal	RSC Advances
Volume	3
Issue number	46
DOIs	https://doi.org/10.1039/c3ra44051f
State	Published - 14 Dec 2013
Externally published	Yes

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AB - The ruthenium carbamate complex derived from 3-trimethoxysilyl-1-propyl amine and carbon dioxide was found to be a novel catalyst for the oxidative cyanation of aromatic and cyclic tertiary amines to corresponding α-amino nitriles in high to excellent yields by using hydrogen peroxide and molecular oxygen as enviro-economic oxidants. The developed protocol suggested an efficient alternative for recycling carbon dioxide.

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A ruthenium-carbamato-complex derived from a siloxylated amine and carbon dioxide for the oxidative α-cyanation of aromatic and cyclic tertiary amines

Abstract

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