A phenoxyl radical complex of copper(II)

Laurent Benisvy, Alexander J. Blake, David Collison, E. Stephen Davies, C. David Garner, Eric J.L. McInnes, Jonathan McMaster, Gavin Whittaker, Claire Wilson

Research output: Contribution to journalArticlepeer-review

107 Scopus citations

Abstract

A new N,O-bidentate pro-ligand (HL), [ML2] (M = Cu, Zn) and [CuL2][BF4] have been synthesised; [CuL2]·4DMF and [CuL2][BF4]·2CH2Cl2 have been crystallographically and spectroscopically characterised; these data indicate that [CuL2]+ cations are constituted as [Cu2+(L)(L-)]+ and involve the phenoxyl radical L.

Original languageEnglish
Pages (from-to)1824-1825
Number of pages2
JournalChemical Communications
Volume18
DOIs
StatePublished - 21 Sep 2001
Externally publishedYes

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