A phenoxyl radical complex of copper(II)

Laurent Benisvy; Alexander J. Blake; David Collison; E. Stephen Davies; C. David Garner; Eric J.L. McInnes; Jonathan McMaster; Gavin Whittaker; Claire Wilson

doi:10.1039/b105186p

A phenoxyl radical complex of copper(II)

Laurent Benisvy, Alexander J. Blake, David Collison, E. Stephen Davies, C. David Garner, Eric J.L. McInnes, Jonathan McMaster, Gavin Whittaker, Claire Wilson

Research output: Contribution to journal › Article › peer-review

108 Scopus citations

Abstract

A new N,O-bidentate pro-ligand (HL), [ML₂] (M = Cu, Zn) and [CuL₂][BF₄] have been synthesised; [CuL₂]·4DMF and [CuL₂][BF₄]·2CH₂Cl₂ have been crystallographically and spectroscopically characterised; these data indicate that [CuL₂]⁺ cations are constituted as [Cu²⁺(L)(L^-)]⁺ and involve the phenoxyl radical L.

Original language	English
Pages (from-to)	1824-1825
Number of pages	2
Journal	Chemical Communications
Volume	18
DOIs	https://doi.org/10.1039/b105186p
State	Published - 21 Sep 2001
Externally published	Yes

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title = "A phenoxyl radical complex of copper(II)",

abstract = "A new N,O-bidentate pro-ligand (HL), [ML2] (M = Cu, Zn) and [CuL2][BF4] have been synthesised; [CuL2]·4DMF and [CuL2][BF4]·2CH2Cl2 have been crystallographically and spectroscopically characterised; these data indicate that [CuL2]+ cations are constituted as [Cu2+(L)(L-)]+ and involve the phenoxyl radical L.",

author = "Laurent Benisvy and Blake, {Alexander J.} and David Collison and Davies, {E. Stephen} and Garner, {C. David} and McInnes, {Eric J.L.} and Jonathan McMaster and Gavin Whittaker and Claire Wilson",

year = "2001",

month = sep,

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doi = "10.1039/b105186p",

language = "אנגלית",

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T1 - A phenoxyl radical complex of copper(II)

AU - Benisvy, Laurent

AU - Blake, Alexander J.

AU - Collison, David

AU - Davies, E. Stephen

AU - Garner, C. David

AU - McInnes, Eric J.L.

AU - McMaster, Jonathan

AU - Whittaker, Gavin

AU - Wilson, Claire

PY - 2001/9/21

Y1 - 2001/9/21

N2 - A new N,O-bidentate pro-ligand (HL), [ML2] (M = Cu, Zn) and [CuL2][BF4] have been synthesised; [CuL2]·4DMF and [CuL2][BF4]·2CH2Cl2 have been crystallographically and spectroscopically characterised; these data indicate that [CuL2]+ cations are constituted as [Cu2+(L)(L-)]+ and involve the phenoxyl radical L.

AB - A new N,O-bidentate pro-ligand (HL), [ML2] (M = Cu, Zn) and [CuL2][BF4] have been synthesised; [CuL2]·4DMF and [CuL2][BF4]·2CH2Cl2 have been crystallographically and spectroscopically characterised; these data indicate that [CuL2]+ cations are constituted as [Cu2+(L)(L-)]+ and involve the phenoxyl radical L.

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DO - 10.1039/b105186p

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SN - 1359-7345

VL - 18

SP - 1824

EP - 1825

JO - Chemical Communications

JF - Chemical Communications

ER -

A phenoxyl radical complex of copper(II)

Abstract

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