TY - JOUR
T1 - A novel route to bicyclic iron tricarbonyl complexes involving π-allyl and σ-components
AU - Eisenstadt, A.
PY - 1973/11/1
Y1 - 1973/11/1
N2 - Nucleophilic attack of CN- on bicyclo[3.2.1]octadienyl-, bicyclo[3.2.2]- nonadienyl-, and 6,7-benzobicyclo[3.2.2]nonadienyliron tricarbonyl tetrafluoroborates, results in mixed-type complexes containing both σ and π-allyl bonds. The cyano group in the products is located exo to the bicyclic ring. In contrast, the three cations react smoothly with I-; carbon monoxide is displaced to give iron complexes containing covalently-bound halogen.
AB - Nucleophilic attack of CN- on bicyclo[3.2.1]octadienyl-, bicyclo[3.2.2]- nonadienyl-, and 6,7-benzobicyclo[3.2.2]nonadienyliron tricarbonyl tetrafluoroborates, results in mixed-type complexes containing both σ and π-allyl bonds. The cyano group in the products is located exo to the bicyclic ring. In contrast, the three cations react smoothly with I-; carbon monoxide is displaced to give iron complexes containing covalently-bound halogen.
UR - http://www.scopus.com/inward/record.url?scp=49549164462&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)80654-3
DO - 10.1016/S0022-328X(00)80654-3
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AN - SCOPUS:49549164462
SN - 0022-328X
VL - 60
SP - 335
EP - 342
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -