TY - JOUR
T1 - A New Synthesis of Key Intermediates for the Preparation of 5,6‐DiHETE and Lipoxin A4
AU - Gigou, Agnès
AU - Lellouche, Jean‐Paul ‐P
AU - Beaucourt, Jean‐Pierre ‐P
AU - Toupet, Loïc
AU - Grée, René
PY - 1989/6
Y1 - 1989/6
N2 - The highly diastereoselective osmylation of a C C bond in proximity to a complex fragment is the key step in the formation of 2 from the butadiene(tricarbonyl)iron complex 1. The diols 2 can be transformed readily into 3, key intermediates in the synthesis of 5,6‐DiHETE and lipoxin A4. R SiPh2tBu; R′ Me; E CO2Me. (Figure Presented.)
AB - The highly diastereoselective osmylation of a C C bond in proximity to a complex fragment is the key step in the formation of 2 from the butadiene(tricarbonyl)iron complex 1. The diols 2 can be transformed readily into 3, key intermediates in the synthesis of 5,6‐DiHETE and lipoxin A4. R SiPh2tBu; R′ Me; E CO2Me. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=0024390539&partnerID=8YFLogxK
U2 - 10.1002/anie.198907551
DO - 10.1002/anie.198907551
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AN - SCOPUS:0024390539
SN - 0570-0833
VL - 28
SP - 755
EP - 757
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 6
ER -