A new etherification reaction in the η4-dienyl-tricarbonyliron series: Access to the 2,5-disubstituted-1,4-dioxane core

J. P. Lellouche, C. Quirosa-Guillou

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The η4-dienyl tricarbonyliron complex 8 has been used as a valuable building block en route to the 2,5-disubstituted-1,4-dioxane 4. Particularly noteful is the new regioselective etherification reaction of 8 with the suitably protected secondary glycerol 11 through the non-isolated organometallic cation 13.

Original languageEnglish
Pages (from-to)977-993
Number of pages17
JournalSynthetic Communications
Volume25
Issue number7
DOIs
StatePublished - 1 Apr 1995
Externally publishedYes

Bibliographical note

Funding Information:
this work and the Servier Research Institute (Suresnes) for its financial support.

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