A New Approach to the Synthesis of Transition Metal Phosphide Nanocrystallites (MoP, MoP2, Cu3P and CuP2) by Using Reaction under Autogenic Pressure at Elevated Temperatures (RAPET) Technique

P. P. George; I. Genish; Shirly Ben David Maklouf; Y. Koltypin; A. Gedanken

doi:10.1142/s0219581x16500307

A New Approach to the Synthesis of Transition Metal Phosphide Nanocrystallites (MoP, MoP₂, Cu₃P and CuP₂) by Using Reaction under Autogenic Pressure at Elevated Temperatures (RAPET) Technique

P. P. George
, I. Genish
, Shirly Ben David Maklouf
, Y. Koltypin
, A. Gedanken

Jawaharlal Nehru Technological University Anantapur

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The reaction under autogenic pressure at elevated temperature (RAPET) technique is proposed for synthesizing a series of metal phosphide nanoparticles such as MoP, MoP₂, Cu₃P and CuP₂ at 850° C for 3.50h by reacting selectively the transition metal powders with elemental phosphorus. The obtained products are characterized by powder X-ray diffraction (PXRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). A reaction mechanism is suggested based on the experimental results.

Original language	English
Article number	1650030
Journal	International Journal of Nanoscience
Volume	16
Issue number	2
DOIs	https://doi.org/10.1142/s0219581x16500307
State	Published - 1 Apr 2017

Bibliographical note

Publisher Copyright:
© 2017 World Scientific Publishing Company.

Keywords

Metal phosphides
RAPET
transition metals

Access to Document

10.1142/s0219581x16500307

Cite this

George, P. P., Genish, I., Maklouf, S. B. D., Koltypin, Y., & Gedanken, A. (2017). A New Approach to the Synthesis of Transition Metal Phosphide Nanocrystallites (MoP, MoP₂, Cu₃P and CuP₂) by Using Reaction under Autogenic Pressure at Elevated Temperatures (RAPET) Technique. International Journal of Nanoscience, 16(2), Article 1650030. https://doi.org/10.1142/s0219581x16500307

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A New Approach to the Synthesis of Transition Metal Phosphide Nanocrystallites (MoP, MoP₂, Cu₃P and CuP₂) by Using Reaction under Autogenic Pressure at Elevated Temperatures (RAPET) Technique. / George, P. P.; Genish, I.; Maklouf, Shirly Ben David et al.
In: International Journal of Nanoscience, Vol. 16, No. 2, 1650030, 01.04.2017.

Research output: Contribution to journal › Article › peer-review

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