A magnetic circular dichroism study of the 3p Rydberg states of acetone

Aharon Gedanken

doi:10.1021/j100264a004

A magnetic circular dichroism study of the 3p Rydberg states of acetone

Aharon Gedanken

Department of Chemistry

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Abstract

The magnetic circular dichroism spectrum of acetone in the energy region of the 3p Rydberg states shows opposite sign B terms. It indicates that two excited states are contributing to the absorption in the region. The states are assigned as the two allowed 3p Rydbergs ¹A₁ and ¹B₂. It is shown, based on a previous ab-initio calculation and a simple B term calculation, that ¹B₂ is the lower energy state.

Original language	English
Pages (from-to)	3781-3782
Number of pages	2
Journal	Journal of Physical Chemistry
Volume	89
Issue number	18
DOIs	https://doi.org/10.1021/j100264a004
State	Published - 1985

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title = "A magnetic circular dichroism study of the 3p Rydberg states of acetone",

abstract = "The magnetic circular dichroism spectrum of acetone in the energy region of the 3p Rydberg states shows opposite sign B terms. It indicates that two excited states are contributing to the absorption in the region. The states are assigned as the two allowed 3p Rydbergs 1A1 and 1B2. It is shown, based on a previous ab-initio calculation and a simple B term calculation, that 1B2 is the lower energy state.",

author = "Aharon Gedanken",

year = "1985",

doi = "10.1021/j100264a004",

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journal = "Journal of Physical Chemistry",

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publisher = "American Chemical Society",

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N2 - The magnetic circular dichroism spectrum of acetone in the energy region of the 3p Rydberg states shows opposite sign B terms. It indicates that two excited states are contributing to the absorption in the region. The states are assigned as the two allowed 3p Rydbergs 1A1 and 1B2. It is shown, based on a previous ab-initio calculation and a simple B term calculation, that 1B2 is the lower energy state.

AB - The magnetic circular dichroism spectrum of acetone in the energy region of the 3p Rydberg states shows opposite sign B terms. It indicates that two excited states are contributing to the absorption in the region. The states are assigned as the two allowed 3p Rydbergs 1A1 and 1B2. It is shown, based on a previous ab-initio calculation and a simple B term calculation, that 1B2 is the lower energy state.

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A magnetic circular dichroism study of the 3p Rydberg states of acetone

Abstract

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