Abstract
The Pauli master equation for intramolecular vibrational relaxation and the heat bath feedback Bloch equations for radiative pumping of polyatomic molecules can be derived by replacing the standard assumption of random matrix element coupling between zero-order vibrational states by an assumption that relaxation is governed by restricted quantum exchange.
| Original language | English |
|---|---|
| Pages (from-to) | 539-542 |
| Number of pages | 4 |
| Journal | Chemical Physics Letters |
| Volume | 82 |
| Issue number | 3 |
| DOIs | |
| State | Published - 15 Sep 1981 |
| Externally published | Yes |
Bibliographical note
Funding Information:This work was supported in part by NSF Grants CHE 73-10020 and CHE 79-10385. Much of the work was carried out durmg d workshop sponsored by NRCC and CECAM at the UniversitC Paris-Sud, France; we thank Dr. Cxl &loser and Dr. William A. Lester for support. We also wish to thank Ms. Sarah Wright for skillful typing of the m.muscript.
Funding
This work was supported in part by NSF Grants CHE 73-10020 and CHE 79-10385. Much of the work was carried out durmg d workshop sponsored by NRCC and CECAM at the UniversitC Paris-Sud, France; we thank Dr. Cxl &loser and Dr. William A. Lester for support. We also wish to thank Ms. Sarah Wright for skillful typing of the m.muscript.
| Funders | Funder number |
|---|---|
| National Science Foundation | CHE 73-10020, CHE 79-10385 |