A circular dichroism study of the oxirane chromophore

A. Gedanken; V. Schurig

doi:10.1021/j100290a011

A circular dichroism study of the oxirane chromophore

A. Gedanken
, V. Schurig

Department of Chemistry

University of Tübingen

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The circular dichroism (CD) spectroscopy of the oxirane chromophore in mono-, di-, and trisubstituted oxiranes was studied. The chirality rule formulated for the n(0) → 3s transition holds for all the molecules examined. The possibility that this rule can be extended to the oxetane chromophore was explored by studying the CD of (S)-2-methyloxetane. The role of a methyl vs. an ethyl group is presented in the CD of cis-(2R,3S)-ethyl-3-methyloxirane.

Original language	English
Pages (from-to)	1324-1327
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	91
Issue number	6
DOIs	https://doi.org/10.1021/j100290a011
State	Published - 1987

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10.1021/j100290a011

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abstract = "The circular dichroism (CD) spectroscopy of the oxirane chromophore in mono-, di-, and trisubstituted oxiranes was studied. The chirality rule formulated for the n(0) → 3s transition holds for all the molecules examined. The possibility that this rule can be extended to the oxetane chromophore was explored by studying the CD of (S)-2-methyloxetane. The role of a methyl vs. an ethyl group is presented in the CD of cis-(2R,3S)-ethyl-3-methyloxirane.",

author = "A. Gedanken and V. Schurig",

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AB - The circular dichroism (CD) spectroscopy of the oxirane chromophore in mono-, di-, and trisubstituted oxiranes was studied. The chirality rule formulated for the n(0) → 3s transition holds for all the molecules examined. The possibility that this rule can be extended to the oxetane chromophore was explored by studying the CD of (S)-2-methyloxetane. The role of a methyl vs. an ethyl group is presented in the CD of cis-(2R,3S)-ethyl-3-methyloxirane.

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A circular dichroism study of the oxirane chromophore

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