Abstract
New ink compositions for direct ink writing (DIW) printing of hydrogels, combining superior rheological properties of cellulose nanocrystals (CNCs) and a water-compatible photoinitiator, are presented. Rapid fixation was achieved by photopolymerization induced immediately after the printing of each layer by 365 nm light for 5 s, which overcame the common height limitation in DIW printing of hydrogels, and enabled the fabrication of objects with a high aspect ratio. CNCs imparted a unique rheological behavior, which was expressed by orders of magnitude difference in viscosity between low and high shear rates and in rapid high shear recovery, without compromising ink printability. Compared to the literature, the presented printing compositions enable the use of low photoinitiator concentrations at a very short build time, 6.25 s/mm, and are also curable by 405 nm light, which is favorable for maintaining viability in bioinks.
Original language | English |
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Pages (from-to) | 6451-6458 |
Number of pages | 8 |
Journal | Langmuir |
Volume | 37 |
Issue number | 21 |
DOIs | |
State | Published - 1 Jun 2021 |
Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2021 American Chemical Society.
Funding
We thank the Ministry of Science Technology and Space, Israel, for financial support (3-15638).
Funders | Funder number |
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Ministry of science and technology, Israel | 3-15638 |