TY - JOUR
T1 - 2,2′,4,4′,6-Penta-tert-butylbenzil
T2 - An unexpected product in the attempted coupling of tri-tert-butylbenzoyl chloride with magnesium-magnesium iodide
AU - Frey, Joseph
AU - Rappoport, Zvi
PY - 1997/5/7
Y1 - 1997/5/7
N2 - Reduction of 2,4,6-tri-tert-butylbenzoyl chloride with Mg-MgI2 in 1:1 diethyl ether-benzene under ultrasonic irradiation gives the hexa-tert-butyl-benzil and -benzoin and also 2,2′,4,4′,6-penta-penta-tert butylbenzil. Possible mechanisms for the loss of the Bu′ group are discussed.
AB - Reduction of 2,4,6-tri-tert-butylbenzoyl chloride with Mg-MgI2 in 1:1 diethyl ether-benzene under ultrasonic irradiation gives the hexa-tert-butyl-benzil and -benzoin and also 2,2′,4,4′,6-penta-penta-tert butylbenzil. Possible mechanisms for the loss of the Bu′ group are discussed.
UR - http://www.scopus.com/inward/record.url?scp=33748641028&partnerID=8YFLogxK
U2 - 10.1039/a607222d
DO - 10.1039/a607222d
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AN - SCOPUS:33748641028
SN - 0300-922X
SP - 1395
EP - 1397
JO - Journal of the Chemical Society, Perkin Transactions 1
JF - Journal of the Chemical Society, Perkin Transactions 1
IS - 9
ER -