1-(2-Naphthalenyl)benzimidazolium based fluorescent probe for acetate ion in 90% aqueous buffer

Sandeep Kumar; Prabhpreet Singh; Subodh Kumar

doi:10.1016/j.tetlet.2012.02.084

1-(2-Naphthalenyl)benzimidazolium based fluorescent probe for acetate ion in 90% aqueous buffer

Sandeep Kumar, Prabhpreet Singh, Subodh Kumar

Guru Nanak Dev University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A new fluorescent probe 9,10-bis[1-(2-naphthalenylbenzimidazolium)-3- methyl]anthracene 1 has been synthesized which shows highly selective fluorescence quenching with only acetate ions in 90% aqueous buffer at pH 7.4. The structure optimization (DFT) of probe 1 and its 1:1 complex with acetate anion, shows that probe 1 is pre-organized and has to undergo minimal spatial reorganization during complexation with acetate anion.

Original language	English
Pages (from-to)	2248-2252
Number of pages	5
Journal	Tetrahedron Letters
Volume	53
Issue number	17
DOIs	https://doi.org/10.1016/j.tetlet.2012.02.084
State	Published - 25 Apr 2012
Externally published	Yes

Keywords

1-(2-Naphthalenyl)benzimidazolium
Acetate
Anions
Aqueous buffer
Benzimidazolium
Fluorescence

Access to Document

10.1016/j.tetlet.2012.02.084

Cite this

@article{21222beb03064cd1b472ba7664cc4969,

title = "1-(2-Naphthalenyl)benzimidazolium based fluorescent probe for acetate ion in 90% aqueous buffer",

abstract = "A new fluorescent probe 9,10-bis[1-(2-naphthalenylbenzimidazolium)-3- methyl]anthracene 1 has been synthesized which shows highly selective fluorescence quenching with only acetate ions in 90% aqueous buffer at pH 7.4. The structure optimization (DFT) of probe 1 and its 1:1 complex with acetate anion, shows that probe 1 is pre-organized and has to undergo minimal spatial reorganization during complexation with acetate anion.",

keywords = "1-(2-Naphthalenyl)benzimidazolium, Acetate, Anions, Aqueous buffer, Benzimidazolium, Fluorescence",

author = "Sandeep Kumar and Prabhpreet Singh and Subodh Kumar",

year = "2012",

month = apr,

day = "25",

doi = "10.1016/j.tetlet.2012.02.084",

language = "אנגלית",

volume = "53",

pages = "2248--2252",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd.",

number = "17",

}

TY - JOUR

T1 - 1-(2-Naphthalenyl)benzimidazolium based fluorescent probe for acetate ion in 90% aqueous buffer

AU - Kumar, Sandeep

AU - Singh, Prabhpreet

AU - Kumar, Subodh

PY - 2012/4/25

Y1 - 2012/4/25

N2 - A new fluorescent probe 9,10-bis[1-(2-naphthalenylbenzimidazolium)-3- methyl]anthracene 1 has been synthesized which shows highly selective fluorescence quenching with only acetate ions in 90% aqueous buffer at pH 7.4. The structure optimization (DFT) of probe 1 and its 1:1 complex with acetate anion, shows that probe 1 is pre-organized and has to undergo minimal spatial reorganization during complexation with acetate anion.

AB - A new fluorescent probe 9,10-bis[1-(2-naphthalenylbenzimidazolium)-3- methyl]anthracene 1 has been synthesized which shows highly selective fluorescence quenching with only acetate ions in 90% aqueous buffer at pH 7.4. The structure optimization (DFT) of probe 1 and its 1:1 complex with acetate anion, shows that probe 1 is pre-organized and has to undergo minimal spatial reorganization during complexation with acetate anion.

KW - 1-(2-Naphthalenyl)benzimidazolium

KW - Acetate

KW - Anions

KW - Aqueous buffer

KW - Benzimidazolium

KW - Fluorescence

UR - http://www.scopus.com/inward/record.url?scp=84862817111&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2012.02.084

DO - 10.1016/j.tetlet.2012.02.084

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:84862817111

SN - 0040-4039

VL - 53

SP - 2248

EP - 2252

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 17

ER -

1-(2-Naphthalenyl)benzimidazolium based fluorescent probe for acetate ion in 90% aqueous buffer

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this